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Title:
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Bis[(acetato-kappa O-2,O ')bis(4,4 '-dimethyl-2,2 '-bipyridyl-N,N ')zinc(II)] trithionate pentahydrate |
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Author:
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Díaz de Vivar, Enriqueta; Baggio, Sergio; Garland, María Teresa; Baggio, Ricardo
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Abstract:
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The title ionic zinc - acetate complex, [Zn(C2H3O2)(C12H12N2) (2)](2)(S3O6) center dot 5H(2)O, contains a ZnN4O2 nucleus provided by the three bidentate ligands acting in a chelating mode. The trithionate unit, in turn, acts as an isolated charge-balancing counter-ion. The structure has a three-dimensional assembly achieved through three different interaction types, viz. Coulomb, hydrogen bonding and pi-pi. The trithionate group and one of the solvent water molecules are disordered around inversion centers. |
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URI:
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http://www.captura.uchile.cl/handle/2250/86
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Date:
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2005-06 |
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dc.identifier.citation:
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ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 61: M289-M291 Part 6, JUN 2005 |