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Title:
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Bond Fukui Functions As Descriptor of the Electron Density Reorganization in π Conjugated Systems |
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Author:
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Gonzalez-Suarez, M.; Aizman, Arie; Soto-Delgado, Jorge; Contreras, R.
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Abstract:
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The bond Fukui function is introduced and tested as a new reactivity index
capable of predicting the evolution of bond breaking and formation processes during an
organic reaction involving π conjugated systems. As an illustration, we examine many cases
where substituted ethylenes and dienes may respond to different reagents to yield
cycloaddition, Michael addition, and other reactions at double bonds. |
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URI:
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http://www.captura.uchile.cl/handle/2250/16593
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Date:
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2011-11-29 |
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dc.identifier.citation:
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J. Org. Chem., Vol. 77, p. 90−95, 2012 |