TRIAMMINE COBALT(III)-L-MALATE - MALATE ION AS A TRIDENTATE LIGAND

Cómo citar
Cómo citar

TRIAMMINE COBALT(III)-L-MALATE - MALATE ION AS A TRIDENTATE LIGAND

.
Copiar
Título: TRIAMMINE COBALT(III)-L-MALATE - MALATE ION AS A TRIDENTATE LIGAND
Autor: Bunel, Sergio; Ibarra, Carmen; Calvo Pérez, Víctor; Blasko, Andrei; Bunton, Clifford A.; Keder, N. L.
Resumen: The crystal structure of the title compound has been determined from single crystal X-ray diffraction data. There is little angle strain in the complex which has two carboxylate ions and one alkoxide ion bound to cobalt(III). These conclusions agree with IR, CD and NMR spectral data except that H-1 coupling constants show that the conformation of the malate ligand differs slightly in solid and solution. The three ammonia ligands have different H-1 chemical shifts and different rates of hydrogen exchange in D2O.
Descripción: Artículo de publicación ISI
URI: http://www.captura.uchile.cl/handle/2250/13870
Fecha: 1991
Cita del item: POLYHEDRON 10 (20-21): 2495-2500


Archivos vinculados

Formato: Nombre: Tamaño: Descripción: Ver
PDF
BUNEL_1991.pdf
5.176Mb
Abrir / Descargar

Este ítem aparece en la(s) siguiente(s) colección(ones)